Publications by †A. I. Priven concerning glass property models including his structural model

 

Contact: priven@itcwin.com

 

Structural model by A. I. Priven:

All details of A. I. Privenís structural model are published in his Doctoral Thesis, St. Petersburg, 2002 (in Russian). Model calculations can be performed using the SciGlass database.

The model is valid for almost all known types of oxide glasses: silicate, germanate, borate, aluminate, phosphate, vanadate, molybdate, niobate, arsenite, tellurite, tungstate etc., including mixed systems. In total 64 oxides are involved in the calculations: Li2O, Na2O, K2O, Rb2O, Cs2O, Cu2O, Ag2O, Tl2O, BeO, MgO, CaO, SrO, BaO, MnO, CoO, NiO, SnO, ZnO, CdO, PbO, FeO, CuO, B2O3, Al2O3, Ga2O3, Fe2O3, Cr2O3, Ti2O3, In2O3, La2O3, Y2O3, Sc2O3, Gd2O3, Sm2O3, Nd2O3,† Pr2O3, Tb2O3, Dy2O3, Er2O3, Yb2O3, As2O3, Sb2O3, Bi2O3, SiO2, GeO2, ThO2, VO2, HfO2, SeO2, TeO2, VO2, PbO2, TiO2, SnO2, ZrO2, CeO2, MnO2, P2O5, V2O5, Nb2O5, Ta2O5, MoO3, WO3, and SO3.

The prediction accuracy of A. I. Privenís models is summarized in the Table below. The models of Priven are based on different principles from the ones described on other pages of this website. For more information the recent publication in Glass Technology (2004, p 244, see below) is recommended.


Models after A. I. Priven: Standard deviation of residuals (difference between experimental data from SciGlass and calculated property values), Reference: Glass Technology 2004, p 244 (see below)

 

Property and unit

T in oC

Number of compo-

sitions compared

St. dev. of residuals

Density of glasses, g/cm3

20

28284

0.13

Density of melts, g/cm3

800

1000

1200

1400

407

638

555

422

0.14

0.13

0.22

0.13

Total*

2022

0.16

Viscosity characteristics, oC

T3 (103 P)

T7.6 (107.6 P)

T13 (1013 P)

2433

3384

1672

60

45

32

Tg, oC **

-

16679

43

Coefficient of thermal expansion (CTE) of glasses, ppm/K

55 +/- 5

160 +/- 10

210 +/- 10

350 +/- 10

1471

5743

4078

1299

0.96

0.82

0.85

1.01

Total*

14221

0.92

Surface tension of melts, mN/m

900

1200

1400

615

1055

351

28

23

39

Total*

2767

26

Heat capacity of glasses and melts, J/(kg * oC)

20

1000

1200

310

151

121

103

168

111

Total*

1438

114

DСр, J/(g-atom * oC)

Tg

136

2.3

Refractive index (nD)

20

23104

0.017

Mean dispersion (nF‑nC)/104

20

7314

18

Anneís number

20

7162

2.4

Youngís modulus, GPa

20

3108

6.8

Shear modulus, GPa

20

1892

2.4

Poissonís ratio

20

1689

0.04

* Including other temperatures not indicated in the table
** Calculated as T13.3

 

 

Publications by† A. I. Priven concerning glass property models:

 

A. I. Priven: "A new equation describing the temperature dependence of the electrical resistivity of alkali containing silicate melts"; Glass Technology, vol. 46, June 2005, no. 3, p 263-270

http://www.ingentaconnect.com/content/sgt/gt/2005/00000046/00000003/art00004


A. I. Priven: "General Method for Calculating the Properties of Oxide Glasses and Glass-Forming Melts from their Composition and Temperature"; Glass Technology, vol. 45, Dec 2004, no. 6, p 244-254

http://www.sciglass.info/Publications/Priven.pdf

http://www.ingentaconnect.com/content/sgt/gt/2004/00000045/00000006/art00001

 

A. I. Priven: "Calculation of the Viscosity of Glass-forming Melts I: The Li2O-Na2O-K2O-SiO2 System"; Glass Physics and Chemistry, vol. 23, no. 5, 1997, p 344-353

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=5&year=97&page=344

 

A. I. Priven: "Calculation of the Viscosity of Glass-forming Melts: II. The MgO-CaO-SrO-BaO-Al2O3-SiO2 System"; Glass Physics and Chemistry, vol. 23, no. 6, 1997, p 416-428

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=6&year=97&page=416

 

A. I. Priven: "Calculation of the Viscosity of Glass-forming Melts: III. The Alk2O-RO-Al2O3-SiO2 System"; Glass Physics and Chemistry, vol. 24, no. 1, 1998, p 19-30

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=1&year=98&page=19

 

A. I. Priven: "Calculation of the Viscosity of Glass-forming Melts: IV. A Unified Method for Calculating the Viscosity of Silicate and Aluminate Melts"; Glass Physics and Chemistry, vol. 24, no. 1, 1998, p 31-40

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=1&year=98&page=31

 

A. I. Priven: "Calculation of the Viscosity of Glass-Forming Melts: V. Binary Borate Systems"; Glass Physics and Chemistry, vol. 26, no. 6, 2000, p 541-558

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=6&year=0&page=541

http://dx.doi.org/10.1023/A:1007196013464

 

A. I. Priven: "Calculation of the Viscosity of Glass-Forming Melts: VI. The R2O-B2O3-SiO2 and RO-B2O3-SiO2 Ternary Borosilicate Systems"; Glass Physics and Chemistry, vol. 27, no. 4, 2001, p 360-370

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=4&year=1&page=360

http://dx.doi.org/10.1023/A:1011372328059

 

A. I. Priven: "Calculation of the Temperature Coefficient of Viscosity Logarithm dlogh/dlogT for Oxide Melts in the Glass Transition Range from Their Composition"; Glass Physics and Chemistry, vol. 26, no. 5, 2000, p 455-469

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=5&year=0&page=455

 

A. I. Priven: "Comparative Characterization of Methods for Calculating the Viscosity of Silicate Glass-forming Melts"; Glass Physics and Chemistry, vol. 23, no. 5, 1997, p 333-343

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=5&year=97&page=333

 

A. I. Priven: "Calculation of the Properties of Oxide Glasses and Melts from Composition: Problems and Prospects"; Glass Physics and Chemistry, vol. 24, no. 2, 1998, p 67-72

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=2&year=98&page=67

 

A. I. Priven: "A New Equation for Describing the Temperature Dependence of the Viscosity of Glass-forming Melts"; Glass Physics and Chemistry, vol. 25, no. 6, 1999, p 491-497

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=6&year=99&page=491

 

A. I. Priven: "Evaluation of the Fraction of Fourfold-Coordinated Boron in Oxide Glasses from Their Composition"; Glass Physics and Chemistry, vol. 26, no. 5, 2000, p 441-454

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=5&year=0&page=441

 

A. I. Priven: "Calculation of the Heat Capacity of Oxide Glass-Forming Melts and Evaluation of the Heat Capacity Jump in the Glass Transition Range from Chemical Composition"; Glass Physics and Chemistry, vol. 27, no. 5, 2001, p 435-444

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=5&year=1&page=435

http://dx.doi.org/10.1023/A:1012452132634

 

A. I. Priven: "Calculation of Temperature Dependences of the Viscosity and Volume Relaxation Time for Oxide Glass-Forming Melts from Chemical Composition and Dilatometric Glass"; Glass Physics and Chemistry, vol. 27, no. 6, 2001, p 527-542

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=6&year=1&page=527

http://dx.doi.org/10.1023/A:1013298225368

 

A. I. Priven: "Calculation of the Structural Linear Expansion Coefficient from the Chemical Composition of Glasses in the R2O(RO)-Al2O3-B2O3 (R = Li, Na, Ca, and Ba) System"; Glass Physics and Chemistry, vol. 29, no. 1, 2003, p 60-68

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=1&year=3&page=60

http://dx.doi.org/10.1023/A:1022361826966

 

Yu. K. Startsev and A. I. Priven: "Calculation of Properties and Stresses in Glass Layers Modified by Ion Exchange: II. Relaxation of Properties of Thin Layers of Glass After Rapid Changes in Its Composition"; Fizika i Khimiya Stekla, vol. 22, no. 2, 1996, p 137-145

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=2&year=96&page=103

 

S. A. Khalimovskaya-Churkina and A. I. Priven: "Calculation of the Heat Capacity of Oxide Glasses at Temperatures from 100 K to the Lower Boundary of Glass Transition Range"; Glass Physics and Chemistry, vol. 26, no. 6, 2000, p 531-540

http://www.maik.rssi.ru/cgi-bin/search.pl?type=abstract&name=physglas&number=6&year=0&page=531

http://dx.doi.org/10.1023/A:1007144029394